Water Knowledge

Chlorine (Free & Total)

Summary: Public water systems use chlorine (or chloramine) to keep water safe as it travels through pipes. Labs report free chlorine (the active disinfectant) and total chlorine (free + combined forms). Levels can change with distance from the plant, season, and household plumbing. Chlorine has a distinct taste/odor at higher levels but is generally not harmful at the amounts used for disinfection.

Why homeowners should care

Too little chlorine can allow microbial growth; too much can affect taste and odor. If you’re sensitive to chlorine, point-of-use filtration can improve taste while keeping your home’s plumbing protected.

Where chlorine comes from

  • Municipal treatment: Added at the plant to maintain a protective residual throughout the distribution system.
  • Household disinfection: Private well owners may chlorinate temporarily after well work or flooding.
  • Chloramine note: Some cities use chloramine (chlorine + ammonia). Total chlorine captures this combined residual; free chlorine alone may read low in chloraminated systems.

When to test

  • When taste/odor seems stronger than usual.
  • When troubleshooting positive coliform results (checking residual after disinfection).
  • To verify a carbon filter or RO system is removing chlorine before sensitive membranes/appliances.

How we test

HealthWaterLab uses a DPD colorimetric method to measure free and total chlorine. Results help you understand both the active disinfectant and any combined forms (e.g., chloramine).

How to collect a good sample

  • Use the kitchen cold-water tap. Remove aerators if instructed.
  • Run water briefly to bring in fresh water from the line (don’t overflush if you’re characterizing first-draw taste).
  • Fill to the mark; test promptly—chlorine can dissipate with time and air exposure.

How to read your result

  • Free chlorine present, modest level: Normal for city water. If taste bothers you, use a carbon filter at the tap.
  • Total chlorine > free chlorine by a lot: Indicates combined forms (like chloramine). Carbon filtration improves taste/odor.
  • No residual (city water): Could indicate loss of protection in long lines or building plumbing—consider flushing lines and checking with your utility if concerns persist.

Practical next steps

  • Improve taste: Point-of-use activated carbon is very effective for removing chlorine/chloramine taste and odor.
  • Protect RO systems: RO membranes are chlorine-sensitive—use a carbon prefilter and replace it on schedule.
  • After well disinfection: Flush until chlorine dissipates, then collect bacteria samples to verify safety.

FAQ

What’s the difference between free and total chlorine?

Free chlorine is the active disinfectant available to kill microbes. Total chlorine = free chlorine + combined forms (e.g., chloramine). Total helps you see if disinfectant is mostly in combined form.

My water smells like a swimming pool—does that mean it’s “too high”?

Not necessarily. Odor can be noticeable even at normal levels, especially after periods of low use. Try flushing the line and, if sensitive, use a carbon filter for drinking/cooking water.

Does chlorine affect bacteria testing?

Yes. Residual chlorine suppresses microbes. After well disinfection, wait until chlorine dissipates before sampling for total coliform/E. coli, or you may get a false sense of safety.

Do I need to measure ORP?

ORP (Oxidation-Reduction Potential) is a quick indicator of oxidizing power and can help operators tune disinfection, but it doesn’t replace a free/total chlorine test. For homeowners, measuring free and total chlorine plus routine bacteria testing is usually more useful.

Can pitcher or fridge filters remove chlorine/chloramine?

Many do, if they contain sufficient activated carbon and are changed on time. Check the certification and replace cartridges as directed to keep taste/odor control working.

Is chlorine harmful to drink?

At the levels used for municipal disinfection, chlorine is generally considered safe. If you dislike the taste, use carbon filtration at the tap.

Why is my free chlorine low at one faucet but normal at another?

Stagnation, long plumbing runs, or old carbon filters can reduce residual locally. Flush lines and replace filters if needed.

Want to check your chlorine levels or taste/odor issues? Order a free/total chlorine kit and get step-by-step instructions at HealthWaterLab.com.